The Constructing of the Oxide Phase Diagram for Fluoride Adsorption on La-Fe-Al: A Collaborative Study of Density Functional Calculation and Experimentation.

In recent years, fluoride pollution in water is a problem that has attracted much attention from researchers. The removal of fluoride-containing wastewater by adsorption with metal oxide as an adsorbent is the most common treatment method. Based on this, the effect of the doping ratio of La2O3, Fe2O3, and Al2O3 on the fluoride-removal performance was discussed by constructing a phase diagram. In this study, the adsorption mechanism of nanocrystalline lanthanum oxide terpolymer was investigated by density functional theory calculation and experiment. The optimal pH condition selected in the experiment was three, and the adsorption kinetics of fluoride ions were more consistent with the quasi-second-order kinetic model. The adsorption thermodynamics was more consistent with the Langmuir model. When the La-Fe-Al ternary composite oxides achieved the optimal adsorption efficiency for fluoride ions, the mass synthesis ratio was Al2O3:(Fe2O3:La2O3 = 1:2) = 1:100, resulting in a fluoride ion removal rate of up to 99.78%. Density functional calculations revealed that the La-Fe-Al ternary composite oxides had three important adsorption sites for La, Fe, and Al. Among them, the adsorption capacity for HF was Fe2O3 > La2O3 > Al2O3, and for F- was La2O3 > Al2O3 > Fe2O3. This provided good guidance for designing adsorbents to remove fluoride.

Potential electron acceptors for ammonium oxidation in wastewater treatment system under anoxic condition: A review.

Anaerobic ammonium oxidation has been considered as an environmental-friendly and energy-efficient biological nitrogen removal (BNR) technology. Recently, new reaction pathway for ammonium oxidation under anaerobic condition had been discovered. In addition to nitrite, iron trivalent, sulfate, manganese and electrons from electrode might be potential electron acceptors for ammonium oxidation, which can be coupled to traditional BNR process for wastewater treatment. In this paper, the pathway and mechanism for ammonium oxidation with various electron acceptors under anaerobic condition is studied comprehensively, and the research progress of potentially functional microbes is summarized. The potential application of various electron acceptors for ammonium oxidation in wastewater is addressed, and the N2O emission during nitrogen removal is also discussed, which was important greenhouse gas for global climate change. The problems remained unclear for ammonium oxidation by multi-electron acceptors and potential interactions are also discussed in this review.

Iron complex regulated synergistic effect between the current and peroxymonosulfate enhanced ultrafast oxidation of perfluorooctanoic acid via free radical dominant electrochemical reaction.

Iron complex regulated electrochemical reaction was triggered for revealing the reaction mechanism, degradation pathway, and applied potential of perfluorooctanoic acid (PFOA). The increased PMS concentrations, electrode spacing, and current density significantly enhanced PFOA elimination, with current density exhibiting a relatively strong interdependency to PFOA complete mineralization. The synergy between PMS and electrochemical reactions greatly accelerated PFOA decomposition by promoting the generation of key reaction sites, such as those for PMS activation and electrochemical processes, under various conditions. Furthermore, density functional theory calculations confirmed that the reciprocal transformation of Fe2+ and Fe3+ complexes was feasible under the electrochemical effect, further promoting the generation of active sites. The developed electrochemical oxidation with PMS reaction (EO/PMS) system can rapidly decompose and mineralize PFOA while maintaining strong tolerance to changing water matrices and organic and inorganic ions. Overall, it holds promise for use in treating and purifying wastewater containing PFOA.

Ferric and sulfate coupled ammonium oxidation enhanced nitrogen removal in two-stage partial nitrification - Anammox/denitrification process for food waste liquid digestate treatment.

Liquid digestate of food waste is an ammonium-, ferric- and sulfate-laden leachate produced during digestate dewatering, where the carbon source is insufficient for nitrogen removal. A two-stage partial nitrification-anammox/denitrification process was established for nitrogen removal of liquid digestate without pre-treatment (>300 d), through which nitrogen (95 %), biodegradable organics (100 %), sulfate (78 %) and iron (100 %) were efficiently removed. Additional ammonium conversion (20 %N) might be coupled with ferric and sulfate reduction, while produced nitrite could be further converted to di-nitrogen gas through anammox (75 %) and denitrification (25 %). Notably, since increasingly contribution of hydroxylamine producing nitrous oxide, and up-regulated expression of electron transfer and cytochrome c protein, the enhanced ammonium oxidation was probably conducted through extracellular polymeric substances-mediated electron transfer between sulfate/ferric-reducers and aerobic ammonium oxidizers. Thus, the established partial nitrification-anammox/denitrification process might be a cost-efficient nitrogen removal technology for liquid digestate, benefitting to domestic waste recycling and carbon neutralization.

Estimation of potential wildfire behavior characteristics to assess wildfire danger in southwest China using deep learning schemes.

Accurate estimation of potential wildfire behavior characteristics (PWBC) can improve wildfire danger assessment. However, wildfire behavior has been estimated by most fire spread models with immeasurable uncertainties and difficulties in large-scale applications. In this study, a PWBC estimation model (named PWBC-QR-BiLSTM) was proposed by coupling the Bi-directional Long Short-Term Memory (BiLSTM) and quantile regression (QR) methods. Multi-source data, including fuel, weather, topography, infrastructure, and landscape variables, were input into the PWBC-QR-BiLSTM model to estimate the potential rate of spread (ROS) and fire radiative power (FRP) over western Sichuan of China, and then to estimate the probability density of ROS and FRP. Daily ROS and FRP were extracted from the Global Fire Atlas and the MOD14A1/MYD14A1 product. The optimal PWBC-QR-BiLSTM model was determined using the Non-dominated Sorting Genetic Algorithm Ⅱ (NAGA-Ⅱ). Results showed that the PWBC-QR-BiLSTM performed well in estimating potential ROS and FRP with high accuracy (ROS: R2 > 0.7 and MAPE<30%, FRP: R2 > 0.8 and MAPE<25%). The modal PWBC values extracted from the estimated probability density were closer to the observed values, which can be regarded as a good indicator for wildfire danger assessment. The variable importance analysis also verified that fuel and infrastructure variables played an important role in driving wildfire behavior. This study suggests the potential of utilizing artificial intelligence to estimate PWBC and its probability density to improve the guidance on wildfire management.

Copper hexacyanoferrate/carbon sheet combination with high selectivity and capacity for copper removal by pseudocapacitance.

The efficient capture of copper ions (Cu2+) in wastewater has dual significance in pollution control and resource recovery. Prussian blue analog (PBA)-based pseudocapacitive materials with open frameworks and abundant metal sites have attracted considerable attention as capacitive deionization (CDI) electrodes for copper removal. In this study, the efficiency of copper hexacyanoferrate (CuHCF) as CDI electrode for Cu2+ treating was evaluated for the first time upon the successful synthesis of copper hexacyanoferrate/carbon sheet combination (CuHCF/C) by introducing carbon sheet as conductive substrate. CuHCF/C exhibited significant pseudocapacitance and high specific capacitance (52.92 F g-1) through the intercalation, deintercalation, and coupling of Cu+/Cu2+ and Fe2+/Fe3+ redox pairs. At 0.8 an applied voltage and CuSO4 feed liquid concentration of 100 mg L-1, the salt adsorption capacity was 134.47 mg g-1 higher than those of most reported electrodes. Moreover, CuHCF/C demonstrated excellent Cu2+ selectivity in multi-ion coexisting solutions and in actual wastewater experiments. Density functional theory (DFT) calculations were employed to elucidate the mechanism. This study not only reveals the essence of Cu2+ deionization by PBAs pseudocapacitance with promising potential applications but also provides a new strategy for selecting efficient CDI electrodes for Cu2+ removal.

Mechanisms underlying the combination effect of arsenite and high-fat diet on aggravating liver injury in mice.

Arsenic (As) is a highly toxic metalloid that can be found in insufficiently purified drinking water and exerts adverse effects on the physiology of living organisms that can negatively affect human health after subchronic exposure, causing several diseases, such as liver damage. A high-fat diet, which is increasing in frequency worldwide, can aggravate hepatic pathology. However, the mechanisms behind liver injury caused by the combinatory effects of As exposure and a high-fat diet remain unclear. In this study, we investigated such underlying mechanisms by focusing on three different aspects: As biotransformation, pathological liver damage, and differential expression of signaling pathway components. We employed mice that were fed a regular diet or a high-fat diet and exposed them to a range of arsenite concentrations (As(III), 0.05-50 mg/L) for 12 weeks. Our results showed that a high-fat diet increased the absorption of As into the liver and enhanced liver toxicity, which became progressively more severe as the As concentration increased. Co-exposure to a high-fat diet and As(III) activated PI3K/AKT and PPAR signaling as well as fatty acid metabolism pathways. In addition, the expression of proteins related to lipid cell function, lipid metabolism, and the regulation of body weight was also affected. Our study provides insights into the mechanisms that contribute to liver injury from subchronic combinatory exposure to As and a high-fat diet and showcases the importance of a healthy lifestyle, which may be of particular benefit to people living in areas with high As(III) concentrations, as a means to reduce or prevent aggravated liver damage.

Prenatal diagnosis of 7q11.23 microdeletion: Two cases report and literature review.

RATIONALE: Chromosome microdeletions within 7q11.23 can result in Williams-Beuren syndrome which is a rare autosomal dominant disorder. Williams-Beuren syndrome is usually associated with developmental delay, cardiovascular anomalies, mental retardation, and characteristic facial appearance. PATIENT CONCERNS: Two pregnant women underwent amniocentesis for cytogenetic analysis and chromosomal microarray analysis (CMA) because of abnormal ultrasound findings. Case 1 presented subependymal cyst and case 2 presented intrauterine growth restriction, persistent left superior vena cava and pericardial effusion in clinical ultrasound examination. DIAGNOSES: Cytogenetic examination showed that the 2 fetuses presented normal karyotypic results. CMA detected 1.536 Mb (case 1) and 1.409 Mb (case 2) microdeletions in the region of 7q11.23 separately. INTERVENTIONS: Both couples opted for the termination of pregnancies based upon genetic counseling. OUTCOMES: The deleted region in both fetuses overlapped with Williams-Beuren syndrome. To our knowledge, case 1 was the first reported fetus of Williams-Beuren syndrome with subependymal cyst. LESSONS: The genotype-phenotype of Williams-Beuren syndrome is complicated due to the phenotypic diversity. For prenatal cases, clinicians should consider the combination of ultrasonography, traditional cytogenetic, and molecular diagnosis technology when genetic counseling.

Prenatal phenotypes and pregnancy outcomes of fetuses with recurrent 1q21.1 microdeletions and microduplications.

Objective: Chromosomal 1q21.1 deletions and duplications are genomic disorders that are usually diagnosed postnatally. However, the genotype-phenotype correlations of 1q21.1 copy number variants (CNVs) during the prenatal period are still not clear. This study aimed to provide a systematic summary of prenatal phenotypes for such genomic disorders. Methods: In total, 26 prenatal amniotic fluid samples diagnosed with 1q21.1 microdeletions/microduplications were obtained from pregnant women who opted for invasive prenatal testing. Karyotypic analysis and chromosomal microarray analysis (CMA) were performed for all cases simultaneously. The pregnancy outcomes and health conditions after birth in all cases were followed up. Meanwhile, prenatal cases with 1q21.1 microdeletions or microduplications in the literature were retrospectively collected. Results: In total, 11 pregnancies (11/8,252, 0.13%) with 1q21.1 microdeletions and 15 (15/8,252, 0.18%) with 1q21.1 microduplications were identified. Among these 1q21.1 CNVs, 4 cases covered the thrombocytopenia-absent radius (TAR) region, 16 cases covered the 1q21.1 recurrent microdeletion/microduplication region, and 6 cases covered all regions mentioned above. The prenatal abnormal ultrasound findings were recorded in four participants with 1q21.1 deletions and seven participants with 1q21.1 duplications. Finally, three cases with 1q21.1 deletions and five with 1q21.1 duplications terminated their pregnancies. Conclusion: In the prenatal setting, 1q21.1 microdeletions were associated with increased nuchal translucency (NT), anomalies of the urinary system, and cardiovascular abnormalities, while 1q21.1 microduplications were correlated with cardiovascular malformations, nasal bone dysplasia, and increased NT. In addition, cerebral ventriculomegaly might be correlated with 1q21.1 microduplications. Considering the variable expressivity and incomplete penetrance of 1q21.1 CNVs, long-term follow-up after birth should be carried out in these cases.

The model and mechanism of adsorptive technologies for wastewater containing fluoride: A review.

With the continuous development of society, industrialization, and human activities have been producing more and more pollutants. Fluoride discharge is one of the main causes of water pollution. This review summarizes various commonly used and effective fluoride removal technologies, including ion exchange technology, electrochemical technology, coagulation technology, membrane treatment, and adsorption technology, and points out the outstanding advantages of adsorption technology. Various commonly used fluoride removal techniques as well as typical adsorbent materials have been discussed in published papers, however, the relationship between different adsorbent materials and adsorption models has rarely been explored, therefore, this paper categorizes and summarizes the various models involved in static adsorption, dynamic adsorption, and electrosorption fluoride removal processes, such as pseudo-first-order and pseudo-second-order kinetic models, Langmuir and Freundlich isotherm models, Thomas and Clark dynamic adsorption models, including the mathematical equations of the corresponding models and the significance of the models are also comprehensively summarized. Furthermore, this comprehensive discussion delves into the fundamental adsorption mechanisms, quantification of maximum adsorption capacity, evaluation of resistance to anion interference, and assessment of adsorption regeneration performance exhibited by diverse adsorption materials. The selection of the best adsorption model not only predicts the adsorption performance of the adsorbent but also provides a better description and understanding of the details of each part of the adsorption process, which facilitates the adjustment of experimental conditions to optimize the adsorption process. This review may provide some guidance for the development of more cost-effective adsorbent materials and adsorption processes in the future.

Comparison of the effect of two commercialized vitrification carriers on pregnancy outcomes in freeze-thaw cycles.

OBJECTIVE: This study aimed to compare the effects of two brands of commercial vitrification carriers on pregnancy outcomes in freeze-thaw cycles. METHODS: We included 4871 patients who underwent a "freeze all" strategy using the commercial carriers J.Y. straw and OYASHIPS straw in the Reproductive Center of the First Hospital of Jilin University. The pregnancy outcomes of cleavage-stage embryos and blastocysts were studied separately. Detailed data and the safety of children born from mothers with the two types of carriers were also compared. RESULTS: Patients who used J.Y. straw had similar clinical pregnancy and live birth rates with one and two cleavage-stage embryo transplantation to those who used OYASHIPS straw. In patients who had blastocyst transplantation, the clinical pregnancy rate of one blastocyst transplanted in those who used OYASHIPS straw was significantly higher than that in those who used J.Y. straw (57.85% vs 47.09%). Among children born from mothers who used J.Y. straw, the congenital disability rate was significantly higher than that in those with OYASHIPS straw. CONCLUSION: The OYASHIPS straw carrier is cheap and can achieve clinical pregnancy and live birth outcomes comparable to those of J.Y. straw. Therefore, OYASHIPS straw is a good alternative option.

Identification and verification of potential biomarkers in sertoli cell-only syndrome via bioinformatics analysis.

Sertoli cell-only syndrome (SCOS), a severe testicular spermatogenic failure, is characterized by total absence of male germ cells. To better expand the understanding of the potential molecular mechanisms of SCOS, we used microarray datasets from the Gene Expression Omnibus (GEO) and ArrayExpress databases to determine the differentially expressed genes (DEGs). In addition, functional enrichment analysis including the Gene Ontology (GO) and Kyoto Encyclopedia of Genes and Genomes (KEGG) was performed. Protein-protein interaction (PPI) networks, modules, and miRNA-mRNA regulatory networks were constructed and analyzed and the validation of hub genes was performed. A total of 601 shared DEGs were identified, including 416 down-regulated and 185 up-regulated genes. The findings of the enrichment analysis indicated that the shared DEGs were mostly enriched in sexual reproduction, reproductive process, male gamete generation, immune response, and immunity-related pathways. In addition, six hub genes (CCNA2, CCNB2, TOP2A, CDC20, BUB1, and BUB1B) were selected from the PPI network by using the cytoHubba and MCODE plug-ins. The expression levels of the hub genes were significantly decreased in patients with SCOS compared to that in normal spermatogenesis controls as indicated by the microarray data, single-cell transcriptomic data, and clinical sample levels. Furthermore, the potential miRNAs were predicted via the miRNA-mRNA network construction. These hub genes and miRNAs can be used as potential biomarkers that may be related to SCOS. However, it has not been proven that the differential expression of these biomarkers is the molecular pathogenesis mechanisms of SCOS. Our findings suggest that these biomarkers can be serve as clinical tool for diagnosis targets and may have some impact on the spermatogenesis of SCOS from a testicular germ cell perspective.

Nomogram for predicting the risk of preterm birth in women undergoing in vitro fertilization cycles.

BACKGROUND: The aim of this study was to develop a nomogram for predicting the risk of preterm birth in women undergoing in vitro fertilization (IVF) cycles. METHODS: A retrospective study of 4266 live birth cycles collected from January 2016 to October 2021 at the Center for Reproductive Medicine, First Hospital of Jilin University was performed. The sample size was sufficient based on the minimal ten events per variable (EPV) rule. The primary outcome of this study was preterm birth. The cycles were divided into the preterm birth group (n = 827) and the full-term delivery group (n = 3439). A nomogram was established based on the multivariate logistic regression analysis results. The area under the curve (AUC) was calculated to assess the prediction accuracy of the nomogram model. The calibration curve was used to measure the calibration of the nomogram. RESULTS: Multivariate logistic regression analyses showed that female obesity or overweight (OR = 1.366, 95% CI: 1.111-1.679; OR = 1.537, 95% CI: 1.030-2.292), antral follicle count (AFC) of more than 24 (OR = 1.378, 95% CI: 1.035-1.836), multiple pregnancies (OR = 6.748, 95% CI: 5.559-8.190), gestational hypertension (OR = 9.662, 95% CI: 6.632-14.078) and gestational diabetes (OR = 4.650, 95% CI: 2.289-9.445) were the independent risk factors for preterm birth in IVF patients. The area under curve (AUC) under the receiver operating characteristic (ROC) curve in the prediction model was 0.781(95%CI: 0.763-0.799). The calibration curve of the nomogram showed that the prediction model had a good calibration. CONCLUSIONS: We used five risk factors to conduct a nomogram to predict preterm birth rates for patients undergoing IVF cycles. This nomogram can provide a visual assessment of the risk of preterm birth for clinical consultation.

Strategy for Co-Enhancement of Remanence-Coercivity of RE-Fe-B Sintered Magnets with High Ce-Content: Appropriate La Substitution.

The development of low-cost RE-Fe-B sintered magnets with large La/Ce content is of great significance for the balanced utilization of rare earth (RE) resources, but it is limited by reduced magnetic properties. In this work, the coercivity (Hcj ), remanence (Br ), maximum energy product [(BH)max ], and temperature stability are simultaneously enhanced for magnets with LaCe accounting for 40 wt% of the total RE. The synergistic regulation of the REFe2 phase, Ce-valence, and grain boundaries (GBs) in RE-Fe-B sintered magnets is realized for the first time by introducing appropriate La elements. The La elements inhibit the generation of the REFe2 phase and tend to stay in the triple junctions, promoting the segregation of the RE/Cu/Ga elements and contributing to the formation of Ce/Nd/Cu/Ga-rich continuous thicker lamellar GBs, and as a result, weakening the detrimental effect on HA caused by La element substitution and enhancing Hcj . In addition, partial La atoms entering the RE2 Fe14 B phase are beneficial for improving the Br and temperature stability of the magnets and promoting the Ce3+ ion ratio, which also provides additional benefit for Br . The findings provide an effective and feasible way to co-enhance the remanence and coercivity of RE-Fe-B sintered magnets with high Ce content.

Biogas production of food waste with in-situ sulfide control under high organic loading in two-stage anaerobic digestion process: Strategy and response of microbial community.

A two-stage anaerobic digestion process utilizing food waste was investigated in this study, without any additive and co-digestion. Solid content, temperature and pH value were key controlling factors for hydrolysis, which results the optimized food waste hydrolysate with COD/VSfood waste of 2.67. Efficient biogas production was maintained in long-term operation (>150 d) without any additive, and methane production yields up to 699.7 mL·gVS-1·d-1 was achieved under organic loading rate (OLR) of 31.0 gVS·d-1. Methane production can be recovered (70.4 %) after temperature shock within 30 days. This study confirmed the possibility to establish two-stage food waste anaerobic digestion system under high organic load. pH, OLR, and temperature are key factors to maintain stable biogas production, while pH control was performed as a in situ sulfide control technology (75.8 % sulfide reduction). This study provides practical strategies for food waste utilization and decreasing carbon footprint.

Real-Time Forest Fire Detection by Ensemble Lightweight YOLOX-L and Defogging Method.

Forest fires can destroy forest and inflict great damage to the ecosystem. Fortunately, forest fire detection with video has achieved remarkable results in enabling timely and accurate fire warnings. However, the traditional forest fire detection method relies heavily on artificially designed features; CNN-based methods require a large number of parameters. In addition, forest fire detection is easily disturbed by fog. To solve these issues, a lightweight YOLOX-L and defogging algorithm-based forest fire detection method, GXLD, is proposed. GXLD uses the dark channel prior to defog the image to obtain a fog-free image. After the lightweight improvement of YOLOX-L by GhostNet, depth separable convolution, and SENet, we obtain the YOLOX-L-Light and use it to detect the forest fire in the fog-free image. To evaluate the performance of YOLOX-L-Light and GXLD, mean average precision (mAP) was used to evaluate the detection accuracy, and network parameters were used to evaluate the lightweight effect. Experiments on our forest fire dataset show that the number of the parameters of YOLOX-L-Light decreased by 92.6%, and the mAP increased by 1.96%. The mAP of GXLD is 87.47%, which is 2.46% higher than that of YOLOX-L; and the average fps of GXLD is 26.33 when the input image size is 1280 × 720. Even in a foggy environment, the GXLD can detect a forest fire in real time with a high accuracy, target confidence, and target integrity. This research proposes a lightweight forest fire detection method (GXLD) with fog removal. Therefore, GXLD can detect a forest fire with a high accuracy in real time. The proposed GXLD has the advantages of defogging, a high target confidence, and a high target integrity, which makes it more suitable for the development of a modern forest fire video detection system.

Bioaccumulation determines the toxicity of carbon dots to two marine dinoflagellates.

With the ever-increasing application of carbon dots (CDs), a substantial amount will be released and assemble in the aquatic environment. Nevertheless, potential photodegradation of CDs in the aquatic environment, their accumulation and impacts in aquatic organisms remain unclear. Our study examined the toxicity of CDs to two marine dinoflagellates Prorocentrum micans and Prorocentrum donghaiense. Their bioaccumulation including the uptake and elimination kinetics was also determined. Significant photodegradation of CDs in seawater was observed. Moreover, both the degraded CDs and their photodegradation products were toxic to the dinoflagellates. Although P. donghaiense was more sensitive to CDs than P. micans with the median effect concentration 17.0 and 99.0 mg L-1, respectively, such sensitivity difference disappeared when the toxicity data were plotted against cellularly accumulated CDs instead of their concentration in the experimental medium. Therefore, the higher sensitivity of P. donghaiense was attributable to its higher accumulation of CDs. Overall, the photodegradation and bioaccumulation of CDs should be considered when evaluating their environmental risks.

Desulfurization of hydrophilic and hydrophobic volatile reduced sulfur with elemental sulfur production in denitrifying bioscrubber.

Volatile reduced sulfur compounds were odor and irritating toxic gas, which were commonly produced during waste and wastewater treatment. The autotrophic sulfide denitrifiers converted sulfide as alternative electron acceptor to reduce nitrate, which achieved simultaneous denitrification and sulfur oxidation. In this study, to investigate the effect of sulfur compounds solubility, S/N and oxygen on sulfur and nitrogen removal, a bioscrubber was studied for treatment of hydrophilic H2S and hydrophobic CS2. Both H2S and CS2 could be efficiently removed (99%), with the highest sulfide loading of 46.9 gS/m3·d. The elemental sulfur production was strongly correlated to S/N ratio (r = 0.969, p = 0.03), the highest elemental sulfur production efficiency achieved 92.0% under S/N ratio of 2.0 for treatment of H2S. Thiobacillus sp. bacteria was the pre-dominated sulfide-dependent denitrifiers (78.2%) before exposing to oxygen, while abundance of Cryseobacterium and unclassified Xanthomonadaceae aerobic sulfide oxidizer dramatically increased up to 40% and 7.3% after aeration. Remarkably increasing production of extracellular polymeric substance (197%) was observed after treatment of CS2, which might promote the hydrolysis of CS2 and stabilization of elemental sulfur. This study demonstrated the possibility to apply sulfide-dependent denitrification process for treatment of both hydrophilic and hydrophobic volatile reduced sulfur waste gas with elemental sulfur recovery.

Associations of sex hormone levels with body mass index (BMI) in men: a cross-sectional study using quantile regression analysis.

Body mass index (BMI) has been increasing globally in recent decades. Previous studies reported that BMI was associated with sex hormone levels, but the results were generated via linear regression or logistic regression, which would lose part of information. Quantile regression analysis can maximize the use of variable information. Our study compared the associations among different regression models. The participants were recruited from the Center of Reproductive Medicine, The First Hospital of Jilin University (Changchun, China) between June 2018 and June 2019. We used linear, logistic, and quantile regression models to calculate the associations between sex hormone levels and BMI. In total, 448 men were included in this study. The average BMI was 25.7 (standard deviation [s.d.]: 3.7) kg m-2; 29.7% (n = 133) of the participants were normal weight, 45.3% (n = 203) of the participants were overweight, and 23.4% (n = 105) of the participants were obese. The levels of testosterone and estradiol significantly differed among BMI groups (all P < 0.05). In linear regression and logistic regression, BMI was associated with testosterone and estradiol levels (both P < 0.05). In quantile regression, BMI was negatively associated with testosterone levels in all quantiles after adjustment for age (all P < 0.05). BMI was positively associated with estradiol levels in most quantiles (≤80th) after adjustment for age (all P < 0.05). Our study suggested that BMI was one of the influencing factors of testosterone and estradiol. Of note, the quantile regression showed that BMI was associated with estradiol only up to the 80th percentile of estradiol.

Promoted Sb removal with hydrogen production in microbial electrolysis cell by ZIF-67-derived modified sulfate-reducing bacteria bio-cathode.

Bio-cathode Microbial electrolysis cell (MEC) has been widely discovered for heavy metals removal and hydrogen production. However, low electron transfer efficiency and heavy metal toxicity limit MEC treatment efficiency. In this study, ZIF-67 was introduced to modify Sulfate-reducing bacteria (SRB) bio-cathode to enhance the bioreduction of sulfate and Antimony (Sb) with hydrogen production in the MEC. ZIF-67 modified bio-cathode was developed from a bio-anode microbial fuel cell (MFC) by operating with an applied voltage of 0.8 V to reverse the polarity. Cyclic voltammetry, linear sweep voltammetry and electrochemical impedance were done to confirm the performance of the ZIF-67 modified SRB bio-cathode. The synergy reduction of sulfate and Sb was accomplished by sulfide metal precipitation reaction from SRB itself. Maximum sulfate reduction rate approached 93.37 % and Sb removal efficiency could reach 92 %, which relies on the amount of sulfide concentration generated by sulfate reduction reaction, with 0.923 ± 0.04 m3 H2/m3 of hydrogen before adding Sb and 0.857 m3 H2/m3 of hydrogen after adding Sb. The hydrogen was mainly produced in this system and the result of gas chromatography (GC) indicated that 73.27 % of hydrogen was produced. Meanwhile the precipitates were analyzed by X-ray diffraction and X-ray photoelectron spectroscopy to confirm Sb2S3 was generated from Sb (V).